An iron-bromoalumanyl complex with a tri-coordinated aluminum was synthesized. Its CO-stretching frequencies are shifted to lower-frequency region compared to those of the related boryl and gallyl complexes. Theoretical investigations suggested the importance of the Br–Al mesomeric effect on the stability of the alumanyl complex.
An iron-bromoalumanyl complex with a tri-coordinated aluminum was synthesized, and its IR and NMR spectroscopic properties were investigated. Theoretical calculations indicated the importance of the Br–Al mesomeric effect on the stability of the alumanyl complex.
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