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CSJ Journals

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2013, Vol.42, No.9

1040-1042

Cold Crystallization in Bis[1-(3-methylphenyl)iminomethylnaphthalen-2-olato]nickel(II) Studied by Thermal Analysis and X-ray Diffraction

Katsunori Iwase 1 , 2 , Hirohiko Houjou 3 , Yasuhisa Yamamura 1 , Kazuya Saito 1
1 Department of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba
2 DENSO CORPORATION
3 Institute of Industrial Science, The University of Tokyo
https://doi.org/10.1246/cl.130409

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Abstract
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Bis[1-(3-methylphenyl)iminomethylnaphthalen-2-olato]nickel(II) was synthesized to see a potential use of this type of compounds as heat-storage materials utilizing cold crystallization. Its thermal, structural, and energetic properties were investigated by thermal analysis, X-ray diffraction, and DFT calculation. Some principles in designing complexes for this purpose are deduced.

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