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2014, Vol.43, No.7

1029-1030
Coordination ProgrammingOpen Access

Abrupt Phase Transition Based on Electron-transfer-coupled Spin Transition in a Cyanide-bridged [Co2Fe2] Tetranuclear Complex

Yoshihiro Sekine 1 , Masayuki Nihei 1 , Hiroki Oshio 1
1 Graduate School of Pure and Applied Sciences, University of Tsukuba
https://doi.org/10.1246/cl.140248

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Abstract
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A cyanide-bridged tetranuclear complex, [Co2Fe2(CN)6(tp*)2(dmbpy)4](PF6)2·4CH3CN (1·4CH3CN) (tp*: hydrotris(3,5-dimethylpyrazol-1-yl)borate and dmbpy: 5,5′-dimethyl-2,2′-bipyridine), was synthesized and its magnetic properties were investigated. Magnetic susceptibility measurements revealed that 1 exhibited an abrupt one-step thermal phase transition based on electron-transfer-coupled spin transition (ETCST) and light-induced ETCST at low temperature.

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