Sign in  |  Register
Cart

CSJ Journals

▾
  • -

1998, Vol.27, No.8

725-726

Synthesis of the First Stable Selenadistibirane and Its Molecular Structure

Tokitoh Norihiro 1 , Sasamori Takahiro 1 , Okazaki Renji 1
1 Department of Chemistry, Graduate School of Science, The University of Tokyo
https://doi.org/10.1246/cl.1998.725

Tools
PDF (168K)
Abstract

Treatment of an extremely hindered 1,3,5-triselena-2,4,6-tristibane derivative with excess amount of hexamethylphosphorous triamide in toluene at 130 °C resulted in the formation of the first stable selenadistibirane derivative as orange crystals. The molecular geometry of this novel heavy atom-containing three-membered ring system was definitively determined by X-ray structural analysis.

<< Previous Synthesis of New Ni-Complexes with a Chalcogen Donor Ligand and Cyano Groups Next >> Characterization of Active Site on Cobalt-Magnesium Oxide by X-Ray Absorption Fine Structure Spectroscopy

Select Issues

▾
  • -

Search for Articles

Advanced

Saved Search

Please login to view your saved searches.

Top Accessed Articles

Most Cited

Related Articles

  1. The First Chemical Trapping of Stibinidene, a Monovalent Antimony Compound
  2. Synthesis and Reactions of the First Stable 1-Germaallene
  3. The First Stable Aromatic S-Nitrosothiol: Synthesis, Structure and Reactivity
  4. Reaction of Stable Silylene–Isocyanide Complexes with Boranes: Synthesis and Properties of the First Stable Silylborane–Isocyanide Complexes
  5. Synthesis, Structure, and Reactions of the First Stable Aromatic S-Nitrosothiol Bearing a Novel Dendrimer-Type Steric Protection Group
MANAGE YOUR ALERTS
RECOMMEND TO LIBRARY