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1999, Vol.28, No.10

1021-1022

Carbene-Lithium Interactions

Arduengo, III Anthony J. 1 , Tamm Matthias 2 , Calabrese Joseph C. 2 , Davidson Fredric 2 , Marshall William J. 2
1 Institut für Anorganische und Analytische Chemie der Technischen UniversitätPostfach 3329, D-38023 Braunschweig, Germany
2 DuPont Central Research, Experimental StationWilmington, Delaware 19880, U.S.A.
https://doi.org/10.1246/cl.1999.1021

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Abstract

The syntheses and characterizations are described for carbene•lithium complexes in which the lithium center is ligated only by carbon atoms. A single crystal X-ray diffraction structure determination on one adduct confirms the coordination environment. The C-Li distance at the carbene center is 215.5 pm. All other coordination to the lithium center originates from a substituted η5-cyclopentadienyl ligand with an average C–Li distance of 225.4 (7) pm.

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