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2006, Vol.35, No.12

1382-1383

Synthesis and Properties of 9-Anthryldiphosphene

Sasamori Takahiro 1 , Tsurusaki Akihiro 1 , Nagahora Noriyoshi 1 , 2 , Matsuda Kazunari 1 , Kanemitsu Yoshihiko 1 , Watanabe Yasuaki 3 , Furukawa Yukio 3 , Tokitoh Norihiro 1
1 Institute for Chemical Research, Kyoto University
2 Institute of Sustainability Science, Kyoto University
3 Department of Chemistry, School of Science and Engineering, Waseda University
https://doi.org/10.1246/cl.2006.1382

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Abstract
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The first stable 9-anthryldiphosphene, TbtP=P(9-Anth) (1: Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl, 9-Anth = 9-anthryl), was synthesized and its properties were revealed by spectroscopic and X-ray crystallographic analyses. The weak fluorescence of 1 was observed in hexane solution.

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