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2007, Vol.36, No.12

1484-1485

Effects of Thermal History on Thermal Anomaly in Solid of Ionic Liquid Compound, [C4mim][Tf2N]

Shimizu Yoshitaka 1 , 2 , Ohte Yoko 1 , Yamamura Yasuhisa 2 , Saito Kazuya 2
1 National Metrology Institute of Japan, National Institute of Advanced Industrial Science and Technology
2 Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba
https://doi.org/10.1246/cl.2007.1484

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Abstract
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Heat capacity of [C4mim][Tf2N] (1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide) was measured by adiabatic calorimetry. Broad heat capacity anomaly and change in spontaneous endothermic effect were observed for crystal phase. The relation between these anomalies and thermal history after crystallization is described.

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