Sign in  |  Register
Cart

CSJ Journals

▾
  • -

2008, Vol.37, No.3

288-289

Fluoride Complexation of Element 104, Rutherfordium (Rf), Investigated by Cation-exchange Chromatography

Ishii Yasuo 1 , 2 , Toyoshima Atsushi 1 , Tsukada Kazuaki 1 , Asai Masato 1 , Toume Hayato 1 , Nishinaka Ichiro 1 , Nagame Yuichiro 1 , Miyashita Sunao 2 , Mori Tomotaka 2 , Suganuma Hideo 2 , Haba Hiromitsu 3 , Sakamaki Masami 4 , Goto Shin-ichi 4 , Kudo Hisaaki 4 , Akiyama Kazuhiko 5 , Oura Yasuji 5 , Nakahara Hiromichi 5 , Tashiro Yuki 6 , Shinohara Atsushi 6 , Schädel Matthias 7 , Brüchle Willy 7 , Pershina Valeria 7 , Kratz Jens V. 8 ... Show all
1 Advanced Science Research Center, Japan Atomic Energy Agency (JAEA)
2 Radiochemical Research Laboratory, Shizuoka University
3 Nishina Center for Accelerator Based Science, RIKEN
4 Department of Chemistry, Niigata University
5 Graduate School of Science and Engineering, Tokyo Metropolitan University
6 Graduate School of Science, Osaka University
7 Gesellschaft für Schwerionenforschung
8 Institut für Kernchemie, Universität Mainz
https://doi.org/10.1246/cl.2008.288

Tools
PDF (73K)
Abstract
figure

We report on new and much more precise cation-exchange data of element 104, rutherfordium (Rf), in the fluoride ion concentration [F−] range of 5.29×10−5−1.04×10−3 M. The result based on one-atom-at-a-time chemistry clearly demonstrates that the distribution coefficients (Kd) decrease with increasing [F−], suggesting successive fluoride complexation of Rf. The complexation of Rf is briefly discussed in terms of fully relativistic density functional calculation theory.

<< Previous Stereoselective Insertion of Rhodium Carbenoid to Water under Control with Intramolecular Participation of Hydroxy Group Next >> Rhodium-catalyzed Addition of Organo[2-(hydroxymethyl)phenyl]dimethylsilanes to Arenesulfonylimines

Select Issues

▾
  • -

Search for Articles

Advanced

Saved Search

Please login to view your saved searches.

Top Accessed Articles

Most Cited

Related Articles

  1. Anionic Fluoro Complex of Element 105, Db
  2. Fluorido Complex Formation of Element 104, Rutherfordium (Rf)
  3. Chloride Complexation of Zr and Hf in HCl Investigated by Extended X-ray Absorption Fine Structure Spectroscopy: Toward Characterization of Chloride Complexation of Element 104, Rutherfordium (Rf)
  4. RIKEN Gas-filled Recoil Ion Separator (GARIS) as a Promising Interface for Superheavy Element Chemistry—Production of Element 104, 261Rf, Using the GARIS/Gas-jet System—
  5. α-Umpolung of Ketones and Aldehydes via the Corresponding Silyl Enol Ether Cation Radicals
MANAGE YOUR ALERTS
RECOMMEND TO LIBRARY