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2009, Vol.38, No.12

1190-1191
Free AccessOpen Access

Effects of Alkyl Length in Ligands in Mixed Valence MMX Complexes: Properties of Pt2(n-HexCS2)4I (n-Hex = n-Hexyl Group)

Ikeuchi Satoaki 1 , 2 , Yamamura Yasuhisa 1 , Mitsumi Minoru 3 , Toriumi Koshiro 3 , Saitoh Hideki 4 , Atake Tooru 5 , Saito Kazuya 1
1 Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba
2 Department of Chemistry, Graduate School of Science, Osaka University
3 Department of Material Science, University of Hyogo
4 Molecular Analysis and Life Science Center, Saitama University
5 Structures and Materials Laboratory, Tokyo Institute of Technology
https://doi.org/10.1246/cl.2009.1190

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Abstract
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The title compound newly synthesized shows a quite different physical properties from similar compounds having shorter alkyl chains in alkyl dithiocarboxylato ligands. This finding demonstrates an important role of ligands and their dynamics in designing physical properties of inorganic complexes.

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