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2011, Vol.40, No.2

196-197

Formation of a Unique Fluorosilene–KF Complex Bearing Bulky Substituents

Mieda Eiko 1 , Sasamori Takahiro 1 , Sase Shohei 2 , Goto Kei 2 , Tokitoh Norihiro 1
1 Institute for Chemical Research, Kyoto University
2 Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
https://doi.org/10.1246/cl.2011.196

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Abstract
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We report here the attempted synthesis of a stable 1-fluoro-2-hydrosilene bearing a Bpq group, which is a bulky aryl group bearing a cavity-shaped framework. We have successfully synthesized an overcrowded benzyldifluorosilane as a precursor. Treatment of the benzyldifluorosilane with 2 equiv of t-BuOK in THF afforded the corresponding benzyl anion, the structure of which showed a unique feature as a fluorosilene–KF complex.

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