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Synthesis of α-Substituted Alkenylammonium Salts through Suzuki–Miyaura and Sonogashira Coupling

Aoi Yoshita , Yota Sakakibara , and Kei Murakami
https://doi.org/10.1246/bcsj.20230018
Abstract

Alkenylammonium salts are a unique class of compounds, wherein an electron-withdrawing ammonio group is attached to an olefin. Although these salts are structurally simple, the synthesis of α-substituted alkenylammonium salts has been sparsely explored. Herein we report the synthesis of α-aryl and α-alkynylated alkenylammonium salts through Suzuki–Miyaura and Sonogashira coupling.

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Alkenylammonium salts are a unique class of compounds, wherein an electron-withdrawing ammonio group is attached to an olefin. Although the salts are structurally simple, the synthesis of α-substituted alkenyl ammonium salts has been sparsely explored. Herein we report the synthesis of α-aryl and alkynylated alkenylammonium salts through Suzuki–Miyaura and Sonogashira coupling.

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