[化学論文のための英語講座] 第26回:助動詞 must
[Rader Jensen's English Course for Chemistry Writing Part 26] Auxiliary Verbs must
...See More2022/07/07
[Rader Jensen's English Course for Chemistry Writing Part 26] Auxiliary Verbs must
...See More2022/07/07
2, in which the η6-arene ligands have long alkyl chains, were prepared. These complexes were dispersed in water to form corresponding micelles. Alkoxy moieties on the η6-arene ligands were reacted with OH− to afford the corresponding phenolic species. Thus, [Ru(p-undecyloxyanisole)(p-cymene)]2+ was converted to [Ru(η6-p-methoxyphenolate)(p-cymene)]+ through the unexpected demethylation by treatment with Na2CO3 with the micelle remaining. The micelle was collapsed when similar ruthenium complex bearing dodecyl 2-(4-methoxyphenoxy)acetate as an arene ligand was treated with Na2CO3 aq.](/na101/home/literatum/publisher/csj/journals/content/cl/0/cl.ahead-of-print/cl.220247/20220705/images/medium/cl-220247figc.gif)
Synthesis of Cationic Sandwich-type Ruthenium Complexes with η6-Arene Ligands Bearing Long Alkyl Chains and Their Behavior in Water
![The first kinetically stabilized 2,2-dihydrosilene 1 bearing 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl (Tbt) and 2,6-diisopropylphenyl (Dip) groups was synthesized as a stable compound. The formation of 1 was confirmed by multinuclear and 2D NMR studies and extensive theoretical calculations.](/na101/home/literatum/publisher/csj/journals/content/cl/0/cl.ahead-of-print/cl.220275/20220630/images/medium/cl-220275figc.gif)
Synthesis of a Kinetically Stabilized 2,2-Dihydrosilene
![Nitrile oxides afford 2-isoxazolines upon [2 + 3] cycloaddition with alkenes. Herein, we prepared oxime-substituted nitrile oxides bound to allylic-alcohol derivatives through a silicon atom and demonstrated their intramolecular cycloaddition reactions. The desired cycloadducts were obtained as single regioisomers in good yields. Furthermore, face-selective cycloaddition reactions were achieved using α-substituted allylic-alcohol derivatives, affording the desired cycloadducts with high diastereoselectivity.](/na101/home/literatum/publisher/csj/journals/content/cl/0/cl.ahead-of-print/cl.220258/20220629/images/medium/cl-220258figc.gif)
Development of Regio- and Face-Selective [2 + 3] Cycloaddition Reactions of Readily Preparable Oxime-Substituted Nitrile Oxides with Silicon-Linked Allylic-Alcohol Moieties for Intramolecular Reactions
![The BSA-MIPs with visualized adsorption and antibacterial ability were prepared by ATRP. The TPE-SO3H with AIE properties was used to visualize the adsorption of BSA-MIPs to BSA. The [AVIM]Cl and [VDIM]Cl) was functional monomer. The results showed that the BSA-MIPs could adsorb BSA through imprinted holes and had antibacterial properties in the process of separation BSA from blood plasma.](/na101/home/literatum/publisher/csj/journals/content/cl/0/cl.ahead-of-print/cl.220262/20220622/images/medium/cl-220262figc.gif)
Molecularly imprinted polymers with visualized adsorption and antibacterial activity for the separation of BSA

Boron-Doped Diamond Powder-Packed Electrolysis Flow Cell

Stable Water-soluble Polyion Complex Micelles Composed of Oppositely Charged Diblock Copolymers and Reinforced by Hydrophobic Interactions

A Fluorescence Study on Guest Release of Reduction-Responsive Host-Guest Conjugates Having a Disulfide Bond

Partially reduced TiO2 aerogel as a catalyst of oxygen reduction reaction in alkaline

Lactuca virosa Leaf-mediated Biosynthesis of Zinc Oxide Nanoparticles and Estimation of Antimicrobial and Anticancer Activities

Fabrication and Electrochemical Characterization of an All-solid-state Battery with an Anti-perovskite Electrode Material (Li2Fe)SO

Competition between Circularly Polarized Light and Molecular Chirality in the Assembly of Main-chain Liquid Crystalline Polymers

Lignin Derived Carbon Electrodes for Hydrocarbon Formation by Electrochemical Reduction of Carbon Dioxide